顾振华


/uploads/image/2019/03/12/b276255ad7576a6f53524928a2e6d4ea.jpg

姓  名:

顾振华

地  址:

安徽省合肥市包河区金寨路96号中国科学技术大学化学系

邮  编:

230026

电  话:

86-0551-63600069

电  邮:

主  页:




/uploads/image/2019/01/08/cfe1cd36d60b7f1c06e6497144a0d8cc.jpg

 教育与科研经历

2012.1 - 至今

中国科学技术大学,化学系,教授、博导

2008.8 - 2011.12

美国加州大学圣巴巴拉分校,化学与生物学系,博士后  导师:a. zakarian

2007.8 - 2008.7

美国加州大学伯克利分校,化学系,博士后  导师:k. p. c. vollhardt

2002.9 - 2007.6

中科院上海有机化学研究所,有机化学,博士  导师:麻生明

1998.9 - 2002.6

南京大学,化学,学士   导师:吴美芳


/uploads/image/2019/01/08/cfe1cd36d60b7f1c06e6497144a0d8cc.jpg

 目前研究方向

我们课题组致力于过渡金属催化的有机合成反应和方法学,包括:

1.

发展新策略高效构建c-c键,c-杂原子;

2.

发展新的基于过渡金属催化的不对称催化反应,特别是阻旋手性等的高效构建;

3.

新催化剂的设计和开发,实现高化学和立体选择性的转化。


/uploads/image/2019/01/08/cfe1cd36d60b7f1c06e6497144a0d8cc.jpg

 代表性论文

1.

hypervalent iodine‐mediated carbon‐carbon bond cleavage and dearomatization of 9h-fluoren-9-ols, ruixian deng, shuming zhan, chunyu li and zhenhua gu*, angew. chem. int. ed., 2020, 59, 3093-3098. doi:10.1002/anie.201913373.

2.

enantioselective carbon-carbon bond cleavage for biaryl atropisomers synthesis, ruixian deng†, junwei xi†, qigang li, zhenhua gu*, chem, 2019, 5, 1834-1846. doi:10.1016/j.chempr.2019.04.008.

3.

enhanced reactivity by torsional strain of cyclic diaryliodonium in cu-catalyzed enantioselective ring-opening reaction, kun zhao†, longhui duan†, shibo xu, julong jiang, yao fu*, and zhenhua gu* (lead contact), chem, 2018, 4, p599–612.

4.

cu-catalyzed enantioselective ring opening of cyclic diaryliodoniums toward the synthesis of chiral diarylmethanes, bin li, zengyin chao, chunyu li, zhenhua gu*j. am. chem. soc., 2018, 140 (30), pp 9400–9403. doi:10.1021/jacs.8b05743.

5.

palladium-catalyzed enantioselective synthesis of 2-aryl cyclohex-2-enone atropisomers: platform molecules for the divergent synthesis of axially chiral biaryl compounds, chongqing pan, zixi zhu, mingkai zhang, zhenhua gu*angew. chem. int. ed. 2017, 56, 4777-4781, doi:10.1002/anie.201701467.

6.

cleavage of the c(o)–s bond of thioesters by palladium/norbornene/copper cooperative catalysis: an efficient synthesis of 2-(arylthio)aryl ketones, fenggang sun, miao li, congfa he, bin wang, bin li, xianwei sui, zhenhua gu*j. am. chem. soc., 2016, 138 (24), pp 7456–7459, doi:10.1002/anie.201509571.

7.

enantioselective synthesis of atropisomeric vinyl arene compounds by palladium catalysis: a carbene strategy, jia feng†, bin li†, yun he, zhenhua gu*angew. chem. int. ed. 2016, 55, 2186 –2190, doi:10.1002/anie.201509571.

8.

palladium-catalyzed catellani ortho-acylation reaction: an efficient and regiospecific synthesis of diaryl ketones, yunze huang, rui zhu, kun zhao, zhenhua gu*angew. chem., int. ed. 2015, 54, 12669-12672 doi:10.1002/anie.201506446.

9.

palladium-catalyzed intramolecular asymmetric c-h functionalization/cyclization reaction of metallocenes: an efficient approach toward the synthesis of planar chiral metallocene compounds, ruixian deng,† yunze huang,† xinna ma, gencheng li, rui zhu, bin wang, yan-biao kang,* and zhenhua gu*j. am. chem. soc. 2014, 136, 4472-4475, doi: 10.1021/ja500699x. (r. d. and y. h. contributed equally)

10.

pd-catalyzed chemoselective catellani ortho-arylation of iodopyrroles: rapid total synthesis of rhazinal, xianwei sui, rui zhu, gencheng li, xinna ma, and zhenhua gu*j. am. chem. soc. 2013, 135, 9318-9321, doi: 10.1021/ja404494u.


顾振华-皇冠体育平台

网站地图